metodologiadiseno

La `operacin unitaria qumica

Metodologa general para el diseo de reactores qumicosEl modelo de diseo puede resumirse en un diagrama de flujo de informacin con las `relaciones de diseo fundamentales, junto a los diferentes tipos de `variables y los datos necesarios para la simulacin:El procedimiento ms general para el `clculo de los reactores qumicos, a partir de la resolucin simultnea de la cintica y los balances de materia y energa, consiste en representar v (Co,x,T) en forma de diagramas vxT (con v como parmetro y Co fijo); sobre dicho diagrama pueden trazarse las lneas de operacin del rgimen trmico T (To,x,q), y con la pauta de temperatura resultante se obtiene la relacin entre la velocidad y la conversin a lo largo de la reaccin v (Co,x).

El tiempo de residencia (o la velocidad espacial) en el reactor se obtienen representando Co/v vs. x, y utilizando la ecuacin de diseo correspondiente (Co,x,v) (para el reactor discontinuo, un tanque continuo agitado, o uno de flujo tubular): (Co,x).

Datos y variables fijas (f)

Variables de estado (4)

Variables de diseo (5-f)

Ec. de diseo:

v (Co,x,T)

T (To,x,q)

( (Co,x,v)

Vr = (Vo

Se desea llevar a cabo el proceso en disolucin acuosa diluida: A = R que se ajusta a una cintica reversible y exotrmica de primer orden: v = -CA/t = k1 CA - k2 CR k1 = 3,1107 e - 5850/T k2 = 1,71018e -14900/T

Curvas isocinticas: x = [k1(T)-v/CoA]/[k1(T)+k2(T)]

v = f (CoA, x, T)

Modelo cinticoEjemplo:Hoja de clculo

La temperatura de la alimentacin es: To = 20C y se desea lograr una conversin en el reactor del 80%:T = To + (q -Hr x)/Cp,mrlHr = -20 kcal/molCp = 1 kcal/lC

a) Reactor de mezcla completa:

El punto final de operacin debecoincidir con el lugar geomtrico develocidades mximas: vmax

b) Reactores de flujo de pistn:

La lnea de operacin se obtienebuscando una velocidad media en elreactor (adiabtico) que haga mnimoel tiempo de residencia: min

El calor intercambiado en cada caso se deduce del balance de energa:q = Hrx + Cp,mrl (T-To) a) q = +26,0 kcal/molA b) q = +34,0 kcal/molA

La relacin entre la velocidad y la conversin a lo largo del reactor viene dada por: v = CoA [ k1 (1-x) - k2 x ]

A) Rgimen isotrmico (T = 62C)reactor de mezcla completa: = CoAx / v = 8,3 min

B) Rgimen adiabtico (To = 54C) reactor de flujo de pistn: = CoA x / v = 2,6 minVo = 1 m3/minVr = 8,3 m3q = +26 Mcal/min 20C62Cx = 0,80x = 0,80Vo = 1 m3/min20C54C70Cq = +34 Mcal/min Vr = 2,6 m3

Grfico2

1.2376237624

1.3097576948

1.3908205841

1.4825796887

1.5873015873

1.70794193

1.8484288355

2.0140986908

2.2123893805

2.4539877301

2.7548209366

3.1397174254

3.6496350365

4.3572984749

5.4054054054

7.1174377224

10.4166666667

CoA/v

Conversin, x

Rgimen isotrmico (T=62C).

Hoja1

Curvas isocinticas: x = [k1(T)-v/CoA]/[k1(T)+k2(T)]k1 = 3,11e7 exp( - 5850/T)

k2 = 1,71e18exp(-14900/T)

CoA = 1 mol/lVelocidad =1.000

T (C)k1 (1/min)k2 (1/min)v (mol/lmin)x

0.00.015310.000001.000-64.2912

5.00.022510.000011.000-43.4017

10.00.032650.000021.000-29.6059

15.00.046750.000061.000-20.3665

20.00.066110.000141.000-14.0956

25.00.092420.000331.000-9.7851

30.00.127780.000751.000-6.7861

35.00.174820.001661.000-4.6758

40.00.236790.003601.000-3.1749

45.00.317670.007611.000-2.0976

50.00.422330.015721.000-1.3187

55.00.556620.031761.000-0.7536

60.00.727550.062811.000-0.3447

65.00.943470.121761.000-0.0531

70.01.214220.231521.0000.1482

75.01.551390.432171.0000.2780

80.01.968480.792571.0000.3508

85.02.481131.429101.0000.3788

90.03.107432.535341.0000.3735

95.03.868084.428361.0000.3457

100.04.786757.620021.0000.3052

Hoja1

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

v (mol/lmin)

x

Temperatura (C)

Conversin, x

v (mol/l.min).

Hoja2

T (C)v=0v=0,002v=0,005v=0,01v=0,02v=0,05v=0,1v=0,2v=0,5v=1v=2

0.00.99980.86920.67330.3469-0.3060-2.2648-5.5293-12.0584-31.6457-64.2912-129.5822

5.00.99960.91080.77760.55560.1116-1.2205-3.4405-7.8807-21.2010-43.4017-87.8030

10.00.99930.93810.84630.69320.3872-0.5310-2.0612-5.1218-14.3033-29.6059-60.2112

15.00.99880.95600.89190.78510.5715-0.0695-1.1378-3.2743-9.6839-20.3665-41.7318

20.00.99790.96770.92240.84700.69600.2432-0.5115-2.0208-6.5488-14.0956-29.1890

25.00.99650.97490.94260.88860.78080.4574-0.0817-1.1598-4.3943-9.7851-20.5666

30.00.99420.97860.95530.91640.83860.60520.2161-0.5619-2.8960-6.7861-14.5664

35.00.99060.97920.96220.93390.87730.70730.4239-0.1427-1.8426-4.6758-10.3421

40.00.98500.97670.96420.94340.90180.77700.56900.1530-1.0950-3.1749-7.3349

45.00.97660.97050.96120.94590.91510.82290.66920.3618-0.5605-2.0976-5.1718

50.00.96410.95960.95270.94130.91850.85000.73580.5076-0.1773-1.3187-3.6015

55.00.94600.94260.93750.92900.91200.86100.77610.60610.0962-0.7536-2.4531

60.00.92050.91800.91420.90790.89520.85730.79400.66750.2879-0.3447-1.6099

65.00.88570.88380.88100.87630.86690.83880.79180.69790.4163-0.0531-0.9918

70.00.83990.83850.83640.83290.82600.80530.77070.70150.49400.1482-0.5435

75.00.78210.78110.77960.77710.77200.75690.73170.68130.53010.2780-0.2262

80.00.71290.71220.71110.70930.70570.69480.67670.64050.53190.3508-0.0114

85.00.63450.63400.63320.63200.62940.62170.60890.58340.50670.37880.1230

90.00.55070.55030.54980.54890.54710.54180.53300.51520.46210.37350.1963

95.00.46620.46600.46560.46500.46380.46020.45420.44210.40600.34570.2252

100.00.38580.38570.38540.38500.38420.38180.37780.36970.34550.30520.2246

Hoja2

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

v=0

v=0,002

v=0,005

v=0,01

v=0,02

v=0,05

v=0,1

v=0,2

v=0,5

v=1

v=2

Temperatura, C

Conversin, x

velocidad (mol/lmin)

Hoja3

isotrmico (T = 62C)adiabtico (To = 54C)

xT (C)k1k2vCoA/vvCoA/v

0.0054.00.52710.02760.80801.23760.52711.8973

0.0555.00.55660.03180.76351.30980.52721.8968

0.1056.00.58760.03650.71901.39080.52521.9040

0.1557.00.62020.04180.67451.48260.52091.9199

0.2058.00.65430.04790.63001.58730.51381.9461

0.2559.00.69010.05490.58551.70790.50381.9848

0.3060.00.72760.06280.54101.84840.49042.0390

0.3561.00.76680.07180.49652.01410.47332.1128

0.4062.00.80800.08200.45202.21240.45202.2125

0.4563.00.85110.09370.40752.45400.42602.3476

0.5064.00.89620.10680.36302.75480.39472.5336

0.5565.00.94350.12180.31853.13970.35762.7965

0.6066.00.99290.13870.27403.64960.31403.1852

0.6567.01.04460.15780.22954.35730.26303.8019

0.7068.01.09860.17950.18505.40540.20404.9025

0.7569.01.15520.20390.14057.11740.13597.3606

0.8070.01.21420.23150.096010.41670.057617.3534

0.8571.01.27590.26270.051519.4175-0.0319-31.3553

0.9072.01.34040.29780.0070142.8571-0.1340-7.4626

0.9573.01.40770.3374-0.0375-26.6667-0.2502-3.9974

1.0074.01.47800.3820-0.0820-12.1951-0.3820-2.6178

Hoja3

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

CoA/v

Conversin, x


0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

CoA/v

Conversin, x

Rgimen adiabtico (To=54C).

Grfico1

1.897259534

1.8968006762

1.9039586971

1.9198857794

1.9461378886

1.9848447331

2.038975666

2.1127710331

2.2124726937

2.347627128

2.5335630312

2.796496226

3.185209515

3.8018866717

4.9025293945

7.3605961443

17.3533848981

CoA/v

Conversin, x


Hoja1


k2 = 1,71e18exp(-14900/T)



0.00.015310.000001.000-64.2912

5.00.022510.000011.000-43.4017

10.00.032650.000021.000-29.6059

15.00.046750.000061.000-20.3665

20.00.066110.000141.000-14.0956

25.00.092420.000331.000-9.7851

30.00.127780.000751.000-6.7861

35.00.174820.001661.000-4.6758

40.00.236790.003601.000-3.1749

45.00.317670.007611.000-2.0976

50.00.422330.015721.000-1.3187

55.00.556620.031761.000-0.7536

60.00.727550.062811.000-0.3447

65.00.943470.121761.000-0.0531

70.01.214220.231521.0000.1482

75.01.551390.432171.0000.2780

80.01.968480.792571.0000.3508

85.02.481131.429101.0000.3788

90.03.107432.535341.0000.3735

95.03.868084.428361.0000.3457

100.04.786757.620021.0000.3052

Hoja1

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

v (mol/lmin)

x

Temperatura (C)

Conversin, x

v (mol/l.min).

Hoja2

T (C)v=0v=0,002v=0,005v=0,01v=0,02v=0,05v=0,1v=0,2v=0,5v=1v=2

0.00.99980.86920.67330.3469-0.3060-2.2648-5.5293-12.0584-31.6457-64.2912-129.5822

5.00.99960.91080.77760.55560.1116-1.2205-3.4405-7.8807-21.2010-43.4017-87.8030

10.00.99930.93810.84630.69320.3872-0.5310-2.0612-5.1218-14.3033-29.6059-60.2112

15.00.99880.95600.89190.78510.5715-0.0695-1.1378-3.2743-9.6839-20.3665-41.7318

20.00.99790.96770.92240.84700.69600.2432-0.5115-2.0208-6.5488-14.0956-29.1890

25.00.99650.97490.94260.88860.78080.4574-0.0817-1.1598-4.3943-9.7851-20.5666

30.00.99420.97860.95530.91640.83860.60520.2161-0.5619-2.8960-6.7861-14.5664

35.00.99060.97920.96220.93390.87730.70730.4239-0.1427-1.8426-4.6758-10.3421

40.00.98500.97670.96420.94340.90180.77700.56900.1530-1.0950-3.1749-7.3349

45.00.97660.97050.96120.94590.91510.82290.66920.3618-0.5605-2.0976-5.1718

50.00.96410.95960.95270.94130.91850.85000.73580.5076-0.1773-1.3187-3.6015

55.00.94600.94260.93750.92900.91200.86100.77610.60610.0962-0.7536-2.4531

60.00.92050.91800.91420.90790.89520.85730.79400.66750.2879-0.3447-1.6099

65.00.88570.88380.88100.87630.86690.83880.79180.69790.4163-0.0531-0.9918

70.00.83990.83850.83640.83290.82600.80530.77070.70150.49400.1482-0.5435

75.00.78210.78110.77960.77710.77200.75690.73170.68130.53010.2780-0.2262

80.00.71290.71220.71110.70930.70570.69480.67670.64050.53190.3508-0.0114

85.00.63450.63400.63320.63200.62940.62170.60890.58340.50670.37880.1230

90.00.55070.55030.54980.54890.54710.54180.53300.51520.46210.37350.1963

95.00.46620.46600.46560.46500.46380.46020.45420.44210.40600.34570.2252

100.00.38580.38570.38540.38500.38420.38180.37780.36970.34550.30520.2246

Hoja2

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

v=0

v=0,002

v=0,005

v=0,01

v=0,02

v=0,05

v=0,1

v=0,2

v=0,5

v=1

v=2

Temperatura, C

Conversin, x


Hoja3



0.0054.00.52710.02760.80801.23760.52711.8973

0.0555.00.55660.03180.76351.30980.52721.8968

0.1056.00.58760.03650.71901.39080.52521.9040

0.1557.00.62020.04180.67451.48260.52091.9199

0.2058.00.65430.04790.63001.58730.51381.9461

0.2559.00.69010.05490.58551.70790.50381.9848

0.3060.00.72760.06280.54101.84840.49042.0390

0.3561.00.76680.07180.49652.01410.47332.1128

0.4062.00.80800.08200.45202.21240.45202.2125

0.4563.00.85110.09370.40752.45400.42602.3476

0.5064.00.89620.10680.36302.75480.39472.5336

0.5565.00.94350.12180.31853.13970.35762.7965

0.6066.00.99290.13870.27403.64960.31403.1852

0.6567.01.04460.15780.22954.35730.26303.8019

0.7068.01.09860.17950.18505.40540.20404.9025

0.7569.01.15520.20390.14057.11740.13597.3606

0.8070.01.21420.23150.096010.41670.057617.3534

0.8571.01.27590.26270.051519.4175-0.0319-31.3553

0.9072.01.34040.29780.0070142.8571-0.1340-7.4626

0.9573.01.40770.3374-0.0375-26.6667-0.2502-3.9974

1.0074.01.47800.3820-0.0820-12.1951-0.3820-2.6178

Hoja3

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

CoA/v

Conversin, x


0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

CoA/v

Conversin, x


Anlisis de la estabilidad del `reactor de mezcla completa no isotrmicoUna vez dimensionado el reactor, los puntos de estado estacionario resultan de los balances:

(1) v (x,T) = CoA x / (2) x = Cp,mrl (T-To) / (q/xf -Hr)

con: CoA = 1 mol/l, = 8,3 min y q = 26 kcal/molA

Puede observarse que el rgimen estacionario es estable en estas condiciones operativas

Reactor de flujo de pistn `con recirculacin: = (R+1) x/v xo = Rxf /(R+1)

Permite un mejor control del proceso, a costa de mayor trasiego, energa y tamao del reactor20C62C62Cxf = 0,80Vo = 1 m3/minVr =3,5 m3q = +42 Mcal/min qr = -16 Mcal/min R=1Xo=0,40

Grfico2

0.0228257269-20

0.0352750712-15

0.0532722384-10

0.0785209173-5

0.11276077640

0.15742854985

0.21318764710

0.279443009315

0.35405186780

0.43343819130.0952380952

0.51315476780.1904761905

0.58868763820.2857142857

0.65615608150.380952381

0.7126464570.4761904762

0.75614605720.5714285714

0.78523551620.6666666667

0.79876382770.7619047619

0.79569666420.8571428571

0.77525271620.9523809524

0.73733764575

0.683135724680

0.6155559185

0.539179735390

0.459559973395

0.3821068855100

x (1)

x (2)

Temperatura, T(C)

Conversin, x

Balances de materia (1) y energa (2)

Hoja1


k2 = 1,71e18exp(-14900/T)



0.00.015310.000001.000-64.2912

5.00.022510.000011.000-43.4017

10.00.032650.000021.000-29.6059

15.00.046750.000061.000-20.3665

20.00.066110.000141.000-14.0956

25.00.092420.000331.000-9.7851

30.00.127780.000751.000-6.7861

35.00.174820.001661.000-4.6758

40.00.236790.003601.000-3.1749

45.00.317670.007611.000-2.0976

50.00.422330.015721.000-1.3187

55.00.556620.031761.000-0.7536

60.00.727550.062811.000-0.3447

65.00.943470.121761.000-0.0531

70.01.214220.231521.0000.1482

75.01.551390.432171.0000.2780

80.01.968480.792571.0000.3508

85.02.481131.429101.0000.3788

90.03.107432.535341.0000.3735

95.03.868084.428361.0000.3457

100.04.786757.620021.0000.3052

Hoja1

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

v (mol/lmin)

x

Temperatura (C)

Conversin, x

v (mol/l.min).

Hoja2

T (C)v=0v=0,002v=0,005v=0,01v=0,02v=0,05v=0,1v=0,2v=0,5v=1v=2

0.00.99980.86920.67330.3469-0.3060-2.2648-5.5293-12.0584-31.6457-64.2912-129.5822

5.00.99960.91080.77760.55560.1116-1.2205-3.4405-7.8807-21.2010-43.4017-87.8030

10.00.99930.93810.84630.69320.3872-0.5310-2.0612-5.1218-14.3033-29.6059-60.2112

15.00.99880.95600.89190.78510.5715-0.0695-1.1378-3.2743-9.6839-20.3665-41.7318

20.00.99790.96770.92240.84700.69600.2432-0.5115-2.0208-6.5488-14.0956-29.1890

25.00.99650.97490.94260.88860.78080.4574-0.0817-1.1598-4.3943-9.7851-20.5666

30.00.99420.97860.95530.91640.83860.60520.2161-0.5619-2.8960-6.7861-14.5664

35.00.99060.97920.96220.93390.87730.70730.4239-0.1427-1.8426-4.6758-10.3421

40.00.98500.97670.96420.94340.90180.77700.56900.1530-1.0950-3.1749-7.3349

45.00.97660.97050.96120.94590.91510.82290.66920.3618-0.5605-2.0976-5.1718

50.00.96410.95960.95270.94130.91850.85000.73580.5076-0.1773-1.3187-3.6015

55.00.94600.94260.93750.92900.91200.86100.77610.60610.0962-0.7536-2.4531

60.00.92050.91800.91420.90790.89520.85730.79400.66750.2879-0.3447-1.6099

65.00.88570.88380.88100.87630.86690.83880.79180.69790.4163-0.0531-0.9918

70.00.83990.83850.83640.83290.82600.80530.77070.70150.49400.1482-0.5435

75.00.78210.78110.77960.77710.77200.75690.73170.68130.53010.2780-0.2262

80.00.71290.71220.71110.70930.70570.69480.67670.64050.53190.3508-0.0114

85.00.63450.63400.63320.63200.62940.62170.60890.58340.50670.37880.1230

90.00.55070.55030.54980.54890.54710.54180.53300.51520.46210.37350.1963

95.00.46620.46600.46560.46500.46380.46020.45420.44210.40600.34570.2252

100.00.38580.38570.38540.38500.38420.38180.37780.36970.34550.30520.2246

Hoja2

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

v=0

v=0,002

v=0,005

v=0,01

v=0,02

v=0,05

v=0,1

v=0,2

v=0,5

v=1

v=2

Temperatura, C

Conversin, x


Hoja3


xT (C)k1k2vCoA/vtvCoA/vt

0.0054.00.52710.02760.80801.23760.0640.52711.89730.095

0.0555.00.55660.03180.76351.30980.0680.52721.89680.095

0.1056.00.58760.03650.71901.39080.0720.52521.90400.096

0.1557.00.62020.04180.67451.48260.0770.52091.91990.097

0.2058.00.65430.04790.63001.58730.0820.51381.94610.098

0.2559.00.69010.05490.58551.70790.0890.50381.98480.101

0.3060.00.72760.06280.54101.84840.0970.49042.03900.104

0.3561.00.76680.07180.49652.01410.1060.47332.11280.108

0.4062.00.80800.08200.45202.21240.1170.45202.21250.114

0.4563.00.85110.09370.40752.45400.1300.42602.34760.122

0.5064.00.89620.10680.36302.75480.1470.39472.53360.133

0.5565.00.94350.12180.31853.13970.1700.35762.79650.150

0.6066.00.99290.13870.27403.64960.2000.31403.18520.175

0.6567.01.04460.15780.22954.35730.2440.26303.80190.218

0.7068.01.09860.17950.18505.40540.3130.20404.90250.307

0.7569.01.15520.20390.14057.11740.4380.13597.36060.618

0.8070.01.21420.23150.096010.41672.4130.057617.35342.628

0.8571.01.27590.26270.051519.4175-0.0319-31.3553

0.9072.01.34040.29780.0070142.8571-0.1340-7.4626

0.9573.01.40770.3374-0.0375-26.6667-0.2502-3.9974

1.0074.01.47800.3820-0.0820-12.1951-0.3820-2.6178

Hoja3

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

CoA/v

Conversin, x

Rgimen isotrmico (T = 62C).

Hoja4

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

CoA/v

Conversin, x

Rgimen adiabtico (To = 54C).

Anlisis de estabilidad: reactor de mezcla completa (t = 8,3 min)

Conversin, x =0.80

q (kcal/molA) =26.0

T(C)k1k2x (1)x (2)

-20.00.00281430.000000050.0228Balance de materia: v(x,T) = Cox(1)/t

-15.00.00440540.000000140.0353Balance de energa: x(2) = Cp(T-To)/(q/x-DHr)

-10.00.00677950.000000420.0533

-5.00.01026660.000001220.0785

0.00.01531270.000003370.1128

5.00.02251290.000008980.1574

10.00.03265100.000023160.2132

15.00.04674710.000057780.2794

20.00.06611410.000139690.35410

25.00.09242340.000327890.43340.0952

30.00.12778160.000748260.51320.1905

35.00.17481820.001662450.58870.2857

40.00.23678610.003600530.65620.3810

45.00.31767430.007610810.71260.4762

50.00.42233460.015719220.75610.5714

55.00.55662250.031756140.78520.6667

60.00.72755200.062813530.79880.7619

65.00.94346640.121762810.79570.8571

70.01.21422280.231523640.77530.9524

75.01.55139250.432171820.7373

80.01.96847630.792572100.6831

85.02.48113381.429104740.6156

90.03.10742772.535340550.5392

95.03.86808144.428360790.4596

100.04.78674987.620021780.3821

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

x (1)

x (2)

Temperatura, T(C)

Conversin, x

Balances de materia (1) y energa (2)

Grfico2

1.2376237624

1.3097576948

1.3908205841

1.4825796887

1.5873015873

1.70794193

1.8484288355

2.0140986908

2.2123893805

2.4539877301

2.7548209366

3.1397174254

3.6496350365

4.3572984749

5.4054054054

7.1174377224

10.4166666667

CoA/v

Conversin, x


Hoja1


k2 = 1,71e18exp(-14900/T)



0.00.015310.000001.000-64.2912

5.00.022510.000011.000-43.4017

10.00.032650.000021.000-29.6059

15.00.046750.000061.000-20.3665

20.00.066110.000141.000-14.0956

25.00.092420.000331.000-9.7851

30.00.127780.000751.000-6.7861

35.00.174820.001661.000-4.6758

40.00.236790.003601.000-3.1749

45.00.317670.007611.000-2.0976

50.00.422330.015721.000-1.3187

55.00.556620.031761.000-0.7536

60.00.727550.062811.000-0.3447

65.00.943470.121761.000-0.0531

70.01.214220.231521.0000.1482

75.01.551390.432171.0000.2780

80.01.968480.792571.0000.3508

85.02.481131.429101.0000.3788

90.03.107432.535341.0000.3735

95.03.868084.428361.0000.3457

100.04.786757.620021.0000.3052

Hoja1

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

v (mol/lmin)

x

Temperatura (C)

Conversin, x

v (mol/l.min).

Hoja2

T (C)v=0v=0,002v=0,005v=0,01v=0,02v=0,05v=0,1v=0,2v=0,5v=1v=2

0.00.99980.86920.67330.3469-0.3060-2.2648-5.5293-12.0584-31.6457-64.2912-129.5822

5.00.99960.91080.77760.55560.1116-1.2205-3.4405-7.8807-21.2010-43.4017-87.8030

10.00.99930.93810.84630.69320.3872-0.5310-2.0612-5.1218-14.3033-29.6059-60.2112

15.00.99880.95600.89190.78510.5715-0.0695-1.1378-3.2743-9.6839-20.3665-41.7318

20.00.99790.96770.92240.84700.69600.2432-0.5115-2.0208-6.5488-14.0956-29.1890

25.00.99650.97490.94260.88860.78080.4574-0.0817-1.1598-4.3943-9.7851-20.5666

30.00.99420.97860.95530.91640.83860.60520.2161-0.5619-2.8960-6.7861-14.5664

35.00.99060.97920.96220.93390.87730.70730.4239-0.1427-1.8426-4.6758-10.3421

40.00.98500.97670.96420.94340.90180.77700.56900.1530-1.0950-3.1749-7.3349

45.00.97660.97050.96120.94590.91510.82290.66920.3618-0.5605-2.0976-5.1718

50.00.96410.95960.95270.94130.91850.85000.73580.5076-0.1773-1.3187-3.6015

55.00.94600.94260.93750.92900.91200.86100.77610.60610.0962-0.7536-2.4531

60.00.92050.91800.91420.90790.89520.85730.79400.66750.2879-0.3447-1.6099

65.00.88570.88380.88100.87630.86690.83880.79180.69790.4163-0.0531-0.9918

70.00.83990.83850.83640.83290.82600.80530.77070.70150.49400.1482-0.5435

75.00.78210.78110.77960.77710.77200.75690.73170.68130.53010.2780-0.2262

80.00.71290.71220.71110.70930.70570.69480.67670.64050.53190.3508-0.0114

85.00.63450.63400.63320.63200.62940.62170.60890.58340.50670.37880.1230

90.00.55070.55030.54980.54890.54710.54180.53300.51520.46210.37350.1963

95.00.46620.46600.46560.46500.46380.46020.45420.44210.40600.34570.2252

100.00.38580.38570.38540.38500.38420.38180.37780.36970.34550.30520.2246

Hoja2

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

00000000000

v=0

v=0,002

v=0,005

v=0,01

v=0,02

v=0,05

v=0,1

v=0,2

v=0,5

v=1

v=2

Temperatura, C

Conversin, x


Hoja3



0.0054.00.52710.02760.80801.23760.52711.8973

0.0555.00.55660.03180.76351.30980.52721.8968

0.1056.00.58760.03650.71901.39080.52521.9040

0.1557.00.62020.04180.67451.48260.52091.9199

0.2058.00.65430.04790.63001.58730.51381.9461

0.2559.00.69010.05490.58551.70790.50381.9848

0.3060.00.72760.06280.54101.84840.49042.0390

0.3561.00.76680.07180.49652.01410.47332.1128

0.4062.00.80800.08200.45202.21240.45202.2125

0.4563.00.85110.09370.40752.45400.42602.3476

0.5064.00.89620.10680.36302.75480.39472.5336

0.5565.00.94350.12180.31853.13970.35762.7965

0.6066.00.99290.13870.27403.64960.31403.1852

0.6567.01.04460.15780.22954.35730.26303.8019

0.7068.01.09860.17950.18505.40540.20404.9025

0.7569.01.15520.20390.14057.11740.13597.3606

0.8070.01.21420.23150.096010.41670.057617.3534

0.8571.01.27590.26270.051519.4175-0.0319-31.3553

0.9072.01.34040.29780.0070142.8571-0.1340-7.4626

0.9573.01.40770.3374-0.0375-26.6667-0.2502-3.9974

1.0074.01.47800.3820-0.0820-12.1951-0.3820-2.6178

Hoja3

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

CoA/v

Conversin, x


0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

CoA/v

Conversin, x


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