Análisis de Cenizas Vegetales

8/17/2019 Análisis de Cenizas Vegetales

1/13

Cenizas vegetalesAnálisis químicos de distintas especies

Esta base de datos contiene distintos análisis de cenizas vegetales y muestra suscomposiciones notoriamente variables según la especie y origen. .

2016

Horacio Ernesto González

De GlazeChem

29/04/2016


2/13

Base de datos que contiene los análisis de las cenizas vegetales

Apple wood ash

Type: ash

Formula: % 1.9 Na2O 11.8 K2O 5.5 MgO 70.9 CaO 2.7 SiO2 4.5 P2O5 2.7 SO3

Molecular Wt.: 100.0Apple wood ash supplies several oxides, especially CaO.

Notes:

Analyses:

Cardew:% 1.9 Na2O 11.8 K2O 5.5 MgO 70.9 CaO 2.7 SiO2 4.5 P2O5 2.7 SO3

(B.C.S., 58 (1959), 59P).

Recalculated on 'washed' basis:

% 6.37 MgO 82.16 CaO 3.13 SiO2 5.21 P2O5 3.13 SO3

Conrad: (adds to 105%)

% 4.9 Na2O 0.89 K2O 3.25 MgO 54.2 CaO 1.98 Al2O3 2.65 SiO2 1.6 P2O5 0.7 Fe2O3 34.7 MnO

Rogers:

% 10.45 Na2O 19.24 K2O 7.46 MgO 63.6 CaO 1.31 SiO2 4.9 P2O5 1.66 Fe2O3 0.93 SO3 0.45 Cl

Hamer & Hamer:

% 6 Na2O 15 K2O 6 MgO 65 CaO 2 SiO2 5 P2O5 1 Fe2O3

Ash wood ash

Type: ash

Formula: % 8 Na2O 17 K2O 12 MgO 27 CaO 1 Al2O3 24 SiO2 7 P2O5 4 Fe2O3

Molecular Wt.: 100.0

Ash wood ash supplies several oxides, especially CaO and SiO2.

Notes:

Analyses:

Hamer & Hamer:

% 8 Na2O 17 K2O 12 MgO 27 CaO 1 Al2O3 24 SiO2 7 P2O5 4 Fe2O3

Bamboo ash

Type: ash

Formula: % 4.8 K2O 0.3 CaO 86.4 SiO2 0.4 Fe2O3 8.1 LOI


Bamboo ash supplies several oxides, especially SiO2.

Notes:

Analyses:

Cardew:

% 4.8 K2O 0.3 CaO 86.4 SiO2 0.4 Fe2O3 8.1 LOI

('Bamboo sugar', Java)

(Bourry, 1st English edition, 1901)

Barley straw ash

Type: ash

Formula: % 5 Na2O 22 K2O 3 MgO 8 CaO 57 SiO2 5 P2O5


Barley straw ash supplies several oxides, especially SiO2 and K2O.

Notes:

Analyses:

Hamer & Hamer:

% 5 Na2O 22 K2O 3 MgO 8 CaO 57 SiO2 5 P2O5


3/13

Beech ash

Type: ash

Formula: % 8.34 Na2O 24.29 K2O 8.20 MgO 42.00 CaO 3.01 SiO2 6.2 P2O5 0.62 Fe2O3 4.52 MnO 2.10 SO3

0.72 Cl


Beech ash supplies several oxides, especially CaO and K2O.

Notes:

Analyses:Rogers:

% 8.34 Na2O 24.29 K2O 8.20 MgO 42.00 CaO 3.01 SiO2 6.2 P2O5 0.62 Fe2O3 4.52 MnO 2.10 SO3 0.72 Cl

Rogers (appendix):

% 4.0 Na2O 16.5 K2O 10.9 MgO 55.5 CaO 5.45 SiO2 5.45 P2O5 1.0 Fe2O3

Birch ash

Type: ash

Formula: % 9 Na2O 22.6 K2O 14.3 MgO 29.6 CaO 11.5 SiO2 7.9 P2O5 1.3 Fe2O3 0.4 MnO 3.4 LOI


Birch ash supplies several oxides, especially CaO and K2O.Notes:

Analyses:

Conrad:

% 9 Na2O 22.6 K2O 14.3 MgO 29.6 CaO 11.5 SiO2 7.9 P2O5 1.3 Fe2O3 0.4 MnO

Rogers (appendix):


Hamer & Hamer:


Cedar ash

Type: ashFormula: % 3.7 Na2O 4.3 K2O 6 MgO 44.2 CaO 0.52 Al2O3 24.28

SiO2 10.6 P2O5 1.01 Fe2O3 0.3 MnO 5.09 LOI


Cedar ash supplies several oxides, especially CaO and SiO2.

Notes:

Analyses:

Conrad:

% 3.7 Na2O 4.3 K2O 6 MgO 44.2 CaO 0.52 Al2O3 24.28 SiO2 10.6 P2O5 1.01 Fe2O3 0.3 MnO

Cherry ashType: ash

Formula: % 1.8 Na2O 21.6 K2O 8.7 MgO 30.3 CaO 24.96 SiO2 7.6 P2O5 2.62 Fe2O3 2.42 LOI


Cherry ash supplies several oxides, especially CaO, SiO2, and K2O.

Notes:

Analyses:

Conrad:



4/13

Coal ash

Type: ash

Formula: 0.24 KNaO 0.20 MgO 0.55 CaO 1.04 Al2O3 3.33 SiO2 0.8 TiO2 0.36 Fe2O3


Coal ash supplies several oxides, especially SiO2, Al2O3,

TiO2, and Fe2O3.

Notes:

Sulfur content of some coals may cause difficulties.Analyses:

Green: (from Bennett and Hawley, "Methods of Silicate Analysis" 1965)

0.24 KNaO 0.20 MgO 0.55 CaO 1.04 Al2O3 3.33 SiO2 0.8 TiO2 0.36 Fe2O3

Common ash

Type: ash

Formula: % 2.33 Na2O 3.91 K2O 3.3 MgO 22.42 CaO 8.91 Al2O3 30.99 SiO2 1.91 P2O5 3.04 Fe2O3 1.26

MnO 21.44 LOI

Molecular Wt.: 99.5

Common ash supplies several oxides, especially SiO2 and CaO.Notes:

Analyses:

Sanders:

% 2.33 Na2O 3.91 K2O 3.3 MgO 22.42 CaO 8.91 Al2O3 30.99 SiO2 1.91 P2O5 3.04 Fe2O3 1.26 MnO 21.44

LOI

Desert plant ash

Type: ash

Formula: % 28.0 Na2O 5.5 K2O 0.5 MgO 21.1 CaO 1.8 P2O5 34.0 CO2

Molecular Wt.: 90.9

Desert plant ash supplies several oxides, especially Na2O and CaO.

Notes:

Analyses:

Tichane (TCB): (adds to 91%)

% 28.0 Na2O 5.5 K2O 0.5 MgO 21.1 CaO 1.8 P2O5 34.0 CO2

Elder ash

Type: ash



Elder ash supplies several oxides, especially CaO.

Notes:

Analyses:

Hamer & Hamer:



5/13

Fern ash

Type: ash

Formula: % 0.56 Na2O 4.81 K2O 7.44 MgO 8.59 CaO 19.32 Al2O3 55.02 SiO2 0.3 TiO2 0.92 P2O5 1.67

Fe2O3 1.36 MnO


Fern ash supplies several oxides, especially SiO2 and Al2O3.

Notes:

Analyses:Rogers (appendix):

% 0.56 Na2O 4.81 K2O 7.44 MgO 8.59 CaO 19.32 Al2O3 55.02 SiO2 0.3 TiO2 0.92 P2O5 1.67 Fe2O3 1.36

MnO

Hamer & Hamer: (Bracken and fern)

% 3 Na2O 26 K2O 8 MgO 12 CaO 10 Al2O3 33 SiO2 6 P2O5 1 Fe2O3 1 MnO

Grass ash

Type: ash

Formula: % 7.956 KNaO 6.159 MgO 14.283 CaO 10.388 Al2O3 61.214

SiO2


Grass ash supplies several oxides, especially SiO2 and CaO.

Notes:

Generic grass ash.

Analyses:

Green: (weed and grass ash)

0.2 KNaO 0.3 MgO 0.5 CaO 0.2 Al2O3 2.0 SiO2

Green: (unwashed lawn clippings, from Leach "A Potter's Book")

0.41 KNaO 0.29 MgO 0.30 CaO 0.27 Al2O3 1.09 SiO2 0.12 P2O5 0.03 Fe2O3

Green: (washed lawn clippings, from Leach "A Potter's Book")

0.15 KNaO 0.32 MgO 0.53 CaO 0.38 Al2O3 1.52 SiO2 0.15 P2O5 0.05 Fe2O3Rogers: (Lawn grass)

% 6.20 Na2O 6.19 K2O 5.65 MgO 12.88 CaO 16.60 Al2O3 39.64 SiO2 9.00 P2O5 3.44 Fe2O3

Hamer & Hamer: (Lawn grass)


Hazel ash

Type: ash



Hazel ash supplies several oxides, especially K2O and CaO.Notes:

Analyses:

Hamer & Hamer:



6/13

Hearth ash

Also called: Dobai

Type: ash


H2O 0.14 MnO

Molecular Wt.: 98.7

Hearth ash supplies several oxides, especially CaO and SiO2.

Notes:Analyses: Cardew:

% 0.55 Na2O 1.49 K2O 5.44 MgO 35.9 CaO 3.69 Al2O3 14.08 SiO2 2.14 P2O5 0.94 Fe2O3 34.32 H2O 0.14

MnO

(Hearth ash ('Dobai'), Japan (E. Kato, Interceram, 2 (1962), 110).)

Heather ash

Type: ash

Formula: % 9 Na2O 12 K2O 10 MgO 21 CaO 41 SiO2 5 P2O5 2 Fe2O3


Heather ash supplies several oxides, especially SiO2 and CaO.Notes:

Analyses:

Hamer & Hamer:


Isu-wood ash

Also called: Issu-wood ash

Type: ash


MnO


Isu-wood ash supplies several oxides, especially CaO and SiO2.

Notes:

Issu (Distylium racemosum) is the source of a very popular wood ash in Japan. Note the incredible variations in

the analyses.

Analyses:

Sanders:


Cardew:

% 0.2 Na2O 1 K2O 6.6 MgO 36.68 CaO 4.16 Al2O3 16.19 SiO2 3.67 P2O5 0.92 Fe2O3 30.08 H2O 0.8 SO3

0.48 MnO(Isu Ash from Hagi, Japan (E. Kato, Interceram, 2 (1962), 110).)

Leach ("A Potter's Book"):

% 0.84 K2O 1.57 MgO 15.95 CaO 0.63 Al2O3 71.96 SiO2 0.42 P2O5 0.28 Fe2O3 8.29 LOI

(from work done by J.B.E. Patterson)

Ivy ash

Type: ash



Ivy ash supplies several oxides, especially CaO, K2O, and Na2O.Notes:

Analyses:

Hamer & Hamer:



7/13

Larch wood ash

Type: ash

Formula: % 9 Na2O 21 K2O 8 MgO 27 CaO 1 Al2O3 11 SiO2 8 P2O5 4 Fe2O3 11 MnO


Larch wood ash supplies several oxides, especially CaO, K2O, SiO2, and MnO.

Notes:

Analyses:Hamer & Hamer:


Mahogany ash

Type: ash

Formula: % 10.98 Na2O 9.49 K2O 4.39 MgO 9.49 CaO 3.81 Al2O3 51.51 SiO2 2.08 P2O5 4.53 Fe2O3

3.72 LOI


Mahogany ash supplies several oxides, especially SiO2.

Notes:Analyses:

Cardew:


(Australian white mahogany)

(Forestry Commission of New South Wales, 1956)

Maple ash

Type: ash

Formula: % 6.04 Na2O 6.2 K2O 12.05 MgO 27.5 CaO 0.9 Al2O3 13.8 SiO2 8.1 P2O5 2.5 Fe2O3 0.5 MnO

22.41 LOI


Maple ash supplies several oxides, especially CaO.

Notes:

Analyses:

Conrad:


Meadow hay ash

Type: ash

Formula: % 7.0 Na2O 25.67 K2O 5.0 MgO 11.56 CaO 29.57 SiO2 6.2 P2O5 1.0 Fe2O3Molecular Wt.: 86.0

Meadow hay ash supplies several oxides, especially SiO2 and K2O.

Notes:

Analyses:

Rogers (appendix):


Hamer & Hamer: (Meadow grass)



8/13

Oak ash

Type: ash

Formula: % 9.12 Na2O 14 K2O 12 MgO 30 CaO 0.1 Al2O3 15.3 SiO2 13.1 P2O5 2.4 Fe2O3 0.1 MnO 3.88 LOI


Oak ash supplies several oxides, especially CaO.

Notes:

Analyses:

Conrad:% 9.12 Na2O 14 K2O 12 MgO 30 CaO 0.1 Al2O3 15.3 SiO2 13.1 P2O5 2.4 Fe2O3 0.1 MnO

Tichane (TCB):

% 3.9 Na2O 9.5 K2O 3.9 MgO 72.5 CaO 2.0 SiO2 5.8 P2O5

Rogers: (English oak)


0.05 CuO 2.61 SO3 1.18 Cl

Rogers (appendix): (China)


Rogers (appendix): (Japan)


Hamer & Hamer:% 6 Na2O 11 K2O 9 MgO 51 CaO 1 Al2O3 10 SiO2 10 P2O5 1 Fe2O3 1 MnO

Oat straw ash

Type: ash



Oat straw ash supplies several oxides, especially SiO2 and K2O.

Notes:

Analyses:

Hamer & Hamer:% 4 Na2O 30 K2O 4 MgO 7 CaO 49 SiO2 5 P2O5 1 Fe2O3

Pine ash

Type: ash


MnO


Pine ash supplies several oxides, especially CaO and SiO2.

Notes:

Analyses:Sanders:


Conrad:

% 8.6 Na2O 26.5 K2O 6.3 MgO 25 CaO 0.4 Al2O3 10 SiO2 8.9 P2O5 4 Fe2O3 5.6 MnO

Tichane (TCB):

% 3.8 Na2O 9.0 K2O 4.5 MgO 39.7 CaO 9.7 Al2O3

24.4 SiO2 3.4 Fe2O3 2.8 P2O5

Rogers:


4.63 SO3 0.52 Cl

Rogers (appendix):% 3.77 Na2O 8.98 K2O 4.45 MgO 39.73CaO 9.71 Al2O3 24.39 SiO2 4.45 P2O5 3.41 Fe2O3 2.74 MnO

Hamer & Hamer: (Scots pine)



9/13

Potato tuber ash

Type: ash

Formula: % 36.315 K2O 2.463 MgO 1.055 CaO 15.819 Al2O3 37.007 SiO2 7.341 P2O5


Potato tuber ash supplies several oxides, especially SiO2 and K2O.

Notes:

Analyses:

Green:0.82 K2O 0.13 MgO 0.04 CaO 0.33 Al2O3 1.31 SiO2 0.11 P2O5

Rice hull ash

Also called: Rice husk ash

Type: ash

Formula: % 0.26 Na2O 0.9 K2O 0.22 MgO 0.48 CaO 1 Al2O3 96 SiO2 0.02 P2O5 0.16 TiO2 0.04 Fe2O3 0.19

MnO 0.96 LOI


Rice hull ash supplies several oxides, especially SiO2.

Notes:Analyses:

Sanders:

% 0.26 Na2O 0.9 K2O 0.22 MgO 0.48 CaO 1 Al2O3 96 SiO2 0.02 P2O5 0.16 TiO2 0.04 Fe2O3 0.19 MnO

0.96 LOI

Conrad:

% 0.26 Na2O 0.9 K2O 0.22 MgO 0.48 CaO 1 Al2O3 96 SiO2 0.02 P2O5 0.04 Fe2O3 0.19 MnO

(Claims this analysis is from from Cardew, but there is no rice hull in Cardew. Looks like it came from Sanders,

but with errors.)

Rogers (appendix):

% 1.35 K2O 1.04 CaO 1.78 Al2O3 94.36 SiO2 0.61 Fe2O3

Rice straw ash

Type: ash

Formula: % 0.36 Na2O 2.48 K2O 1.35 MgO 3.69 CaO 1.36 Al2O3

82.18 SiO2 0.68 P2O5 0.42 Fe2O3 0.38 SO3 7.1 LOI


Rice straw ash supplies several oxides, especially SiO2.

Notes:

Analyses:

Cardew:

% 0.36 Na2O 2.48 K2O 1.35 MgO 3.69 CaO 1.36 Al2O3 82.18 SiO2 0.68 P2O5 0.42 Fe2O3 0.38 SO3 6.2 LOI(Ware-bai)

(E. Kato, Interceram, 2 (1962) 110)

Sanders:

% 0.77 Na2O 3.57 K2O 1.38 MgO 3.07 CaO 1.13 Al2O3 40 SiO2 2.51 P2O5 0.26 Fe2O3 0.30 MnO 47.26 LOI

Rogers:



10/13

Rye straw ash

Type: ash

Formula: % 18.118 K2O 1.254 MgO 3.331 CaO 15.574 Al2O3 57.105 SiO2 2.811 P2O5 1.807 Fe2O3


Rye straw ash supplies several oxides, especially SiO2 and K2O.

Notes:

Analyses:

Green:0.68 K2O 0.11 MgO 0.21 CaO 0.54 Al2O3 3.36 SiO2 0.04 Fe2O3 0.07 P2O5

Rogers:

% 1.74 Na2O 22.56 K2O 3.10 MgO 8.20 CaO 49.27 SiO2 6.53 P2O5 1.91 Fe2O3 4.25 SO3 2.18 Cl

Spruce ash

Type: ash

Formula: % 8.99 Na2O 6.53 K2O 10.99 MgO 8.56 CaO 2.19 Al2O3 19.01 SiO2 8.65 P2O5

2.46 Fe2O3 32.62 LOI


Spruce ash supplies several oxides, especially SiO2 and MgO.Notes:

Analyses:

Conrad:


Rogers:

% 1.37 Na2O 19.66 K2O 11.27 MgO 33.97 CaO 2.73 SiO2 2.12 P2O5 1.42 Fe2O3 22.96 MnO

2.64 SO3 0.07 Cl

Hamer & Hamer:


Straw ashType: ash

Formula: 0.4 KNaO 0.2 MgO 0.4 CaO 2.7 SiO2 0.1 P2O5


Straw ash supplies several oxides, especially SiO2.

Notes:

Generic straw ash.

Analyses:

Green: (straw ash from cereal crops)

0.4 KNaO 0.2 MgO 0.4 CaO 2.7 SiO2 0.1 P2O5

Tallowwood ash

Type: ash

Formula: % 6.84 Na2O 2.41 K2O 25.58 MgO 52.15 CaO 1.09 Al2O3 8.96 SiO2 0.4 P2O5 1.93 SO3 0.38 Cl2

0.18 MnO

Molecular Wt.: 99.9

Tallowwood ash supplies several oxides, especially CaO and MgO.

Notes:

Analyses:

Cardew:

% 6.84 Na2O 2.41 K2O 25.58 MgO 52.15 CaO 1.09 Al2O3 8.96 SiO2 0.4 P2O5 1.93 SO3 0.38 Cl2 0.18 MnO(Eucalyptus microscorys III (Tallowwood) Forestry Commission

of New South Wales, 1956)


11/13

Thatching grass ash

Type: ash


76.96 SiO2 1.58 P2O5 0.22 TiO2 1.06 Fe2O3 0.15 SO3

0.67 MnO 1.4 LOI


Thatching grass ash supplies several oxides, especially SiO2.Notes:

Analyses:

Cardew:

% 0.22 Na2O 2.55 K2O 3.67 MgO 6.14 CaO 5.42 Al2O3 76.96 SiO2 1.58 P2O5 0.22 TiO2 1.06 Fe2O3

0.15 SO3 0.67 MnO 1.4 LOI

(Abuja, Nigeria. Wahsed and calcined at 900C)

(Overseas Geological Surveys, London, 1966)

Turpentine ash

Type: ash

Formula: % 4.08 Na2O 1.2 K2O 1.03 MgO 1.88 CaO 1.26 Al2O3 89.74 SiO2 0.39 P2O5 0.42 LOIMolecular Wt.: 100.0

Turpentine ash supplies several oxides, especially SiO2.

Notes:

Analyses:

Cardew:

% 4.08 Na2O 1.2 K2O 1.03 MgO 1.88 CaO 1.26 Al2O3 89.74 SiO2 0.39 P2O5

(Australian turpentine)

(Forestry Commission of New South Wales, 1956)

Walnut ashType: ash

Formula: % 4.9 Na2O 14.7 K2O 6.6 MgO 38.7 CaO 0.5 Al2O3 16 SiO2 6.5 P2O5 1.9 Fe2O3 0.42 MnO 9.78

LOI


Walnut ash supplies several oxides, especially CaO, K2O, and SiO2.

Notes:

Analyses:

Conrad:

% 4.9 Na2O 14.7 K2O 6.6 MgO 38.7 CaO 0.5 Al2O3 16 SiO2 6.5 P2O5 1.9 Fe2O3 0.42 MnO


12/13

Wheat straw ash

Type: ash

Formula: % 2.8 Na2O 11.5 K2O 2.5 MgO 6.1 CaO 66.2 SiO2 5.4 P2O5

2.8 SO3 3.8 S


Wheat straw ash supplies several oxides, especially SiO2 and K2O.

Notes:

Analyses:Cardew:

% 2.8 Na2O 11.5 K2O 2.5 MgO 6.1 CaO 66.2 SiO2 5.4 P2O5 2.8 SO3 3.8 S

(Air dried)

(B.C.S., (1959), 59P)

Green:

0.67 K2O 0.14 MgO 0.19 CaO 0.71 Al2O3 4.95 SiO2 0.10 P2O5

Tichane (TCB):

% 2.8 Na2O 11.5 K2O 2.5 MgO 6.1 CaO 66.0 SiO2 5.4 P2O5 2.8 LOI

Rogers:


Hamer & Hamer:% 2 Na2O 13 K2O 4 MgO 6 CaO 70 SiO2 5 P2O5

Willow ash

Type: ash


4.44 SiO2 10.00 P2O5 1.25 Fe2O3 0.18 MnO 1.22 SO3 0.08

Cl

Molecular Wt.: 98.0

Willow ash supplies several oxides, especially K2O, CaO, and P2O5.

Notes:

Analyses:Rogers:


1.22 SO3 0.08 Cl

Hamer & Hamer:


Wood ash

Type: ash

Formula: % 12.452 KNaO 6.427 MgO 71.54 CaO 9.581 SiO2


Wood ash supplies several oxides, especially CaO.

Notes:

Generic wood ash.

Analyses:

Green:

0.1 KNaO 0.1 MgO 0.8 CaO 0.1 SiO2


13/13

This database contains analyses of plant ashes. Plant ashes have

notoriously variable compositions, as you may see by comparing some of

the analyses included here. Some factors that cause this variation

include:

- different soils lead to different nutrient uptake

- different parts of the plant concentrate different chemical compounds- plants do different things at different times of the year

- older and younger plants have different compositions

- the degree of washing of the ash leads to different flux amounts

This topic is discussed at greater length in "Ash Glazes" (Tichane)

and "Ash Glazes" (Rogers).

Sources of analyses:

Michael Cardew, "Pioneer Pottery" (1969)

Herbert H. Sanders. "The World of Japanese Ceramics" (?)

John W. Conrad, "Advanced Ceramic Manual" (1987)

David Green, "A Handbook of Pottery Glazes" (1979)

Robert Tichane, "Those Celadon Blues" (1978)

Phil Rogers, "Ash Glazes" (1991)

Frank and Janet Hamer, "The Potter's Dictionary of Materials and

Techniques" 4th edition (1997)

More ash analyses can be obtained from Robert Tichane, "Ash Glazes"

(1987). Tichane in turn refers to two sources: Thorpe's "Dictionary of

Applied Chemistry" (1937?) contains analyses of ash from many

vegetable materials. The second and most complete source (also used by

Thorpe) is Emil Wolff's "Aschen Analysen" (1880), in German. This is

reportedly the most comprehensive compilation of ash analyses in

existence.

A table of Australian wood ash analyses can be found on pg. 199 of Ian

Currie's "Stoneware Glazes" 2nd ed. (1985). The table contains about

30 analyses.

Original en: “GlazeChem ceramic glaze database” año 2001

Recopilacion HEG 2016

Análisis de Cenizas Vegetales

Documents

Transcript of Análisis de Cenizas Vegetales