(2013-II) logk (3 reacciones)

7/24/2019 (2013-II) logk (3 reacciones)

1/8

Especie

65.04 -98

-501.517 71.291

-656.762 20

-372.709 108.4

-527.907 -49.999

-519.074 87.864

12.44 67

-237.141 69.95

CuS -56.611 67.27

H+ 0 0

T (C) T (K) 1/T

5 278.15 0.0035951825 -185.663

10 283.15 0.003531697 -186.804515 288.15 0.0034704147 -187.946

20 293.15 0.0034112229 -189.0875

25 298.15 0.0033540164 -190.229

30 303.15 0.003298697 -191.3705

35 308.15 0.0032451728 -192.512

40 313.15 0.0031933578 -193.6535

45 318.15 0.0031431715 -194.795

50 323.15 0.0030945381 -195.9365

55 328.15 0.0030473869 -197.078

60 333.15 0.0030016509 -198.219565 338.15 0.0029572675 -199.361

70 343.15 0.0029141775 -200.5025

75 348.15 0.0028723251 -201.644

80 353.15 0.0028316579 -202.7855

85 358.15 0.0027921262 -203.927

90 363.15 0.0027536831 -205.0685

95 368.15 0.0027162841 -206.21

25 !/"#$ S25 !/"#$

Cu +2

Cu(%H)3

-

Cu(%H)4

-2

Cu(%H)2 (&c)

C%32-

CuC%3

HS-

H2%

'si"p$ic (K*/"#$)

28

30

32

34

36

(,) 6392.0484793162, + 11.9457144842

1

Cu(OH)4(-2a)+2H(+a)=Cu(OH)2+2H2O

# ()


2/8

# () + (1/T)

11.946 6392

% error

228.3054566235 0.002390111

-122.1604284897 0.0007584316

Sp#"ei# */"#$

Hp#"ei# K*/"#$

0.0026 0.0028 0.003 0.0032 0.0034 0.0036

1/T


3/8

8.3

T(K) 298.15

() # () ()

80.4207662936 34.9262950318 -195.54456 84.7010086003

79.4863721175 34.5204927971 -196.92667 83.793412746978.5844052943 34.1287735829 -198.30878 82.9173142335

77.7132065701 33.7504167844 -199.69089 82.0711013935

76.8712279943 33.3847501351 -201.073 81.2532706711

76.0570237407 33.0311457206 -202.45511 80.4624177065

75.2692418221 32.6890163804 -203.83722 79.6972292871

74.5066165989 32.3578124542 -205.21933 78.9564760719

73.7679619941 32.0370188353 -206.60144 78.2390060004

73.0521653378 31.7261522973 -207.98355 77.5437383139

72.3581817748 31.4247590653 -209.36566 76.8696581236

71.6850291757 31.1324126061 -210.74777 76.215811467471.0317834995 30.8487116136 -212.12988 75.5813008058

70.3975745617 30.5732781715 -213.51199 74.9652809109

69.7815821667 30.3057560735 -214.8941 74.3669551104

69.1830325692 30.0458092861 -216.27621 73.7855718499

68.6011952319 29.7931205412 -217.65832 73.2204215438

68.0353798507 29.5473900433 -219.04043 72.6708336858

67.4849336229 29.308334284 -220.42254 72.1361741956

'si"p$ic (K*/"#$)

30

32

34

36

38

(,) 6208.7252280598, + 14.4636806357

1

Cu(OH)3(-a)+CO3(-2a)+3H(+a)=CuCO3+3H2

# ()


4/8

# () + (1/T)

14.464 6208.7

% error

276.428103516 0.0022080428

-118.657298555 0.0004063324

Sp#"ei# */"#$

Hp#"ei# K*/"#$

0.0038 0.0026 0.0028 0.003 0.0032 0.0034 0.0036

1/T


5/8

-190.229 228.3 -122.161355

-201.073 276.422 -118.6577807

-134.091 98.27 -104.7917995

# () () # ()

36.7851806467 -132.1256 57.2307998848 24.8550205849

36.3910167758 -132.61695 56.4292628753 24.506917484636.0105320259 -133.1083 55.6555425241 24.1708950055

35.6430264589 -133.59965 54.9082154989 23.8463350023

35.2878470891 -134.091 54.1859539449 23.5326607949

34.9443840105 -134.58235 53.4875176113 23.2293337493

34.6120669024 -135.0737 52.8117467436 22.9358501904

34.2903618686 -135.56505 52.1575556577 22.6517386117

33.9787685756 -136.0564 51.5239269194 22.3765571471

33.6768176559 -136.54775 50.909906064 22.1098912778

33.3840683489 -137.0391 50.3145967995 21.8513517492

33.1001063541 -137.53045 49.737156641 21.600572674732.824541875 -138.0218 49.1767929325 21.3572098083

32.5570078339 -138.51315 48.632759217 21.1209389677

32.2971582404 -139.0045 48.1043519187 20.8914545938

32.0446666985 -139.49585 47.5909073076 20.6684684324

31.7992250391 -139.9872 47.091798718 20.4517083261

31.5605420651 -140.47855 46.606433997 20.2409171061

31.3283423988 -140.9699 46.134253161 20.0358515745

' 298.15 K (K*/"#$) S 298.15 K (*/"#$) H 298.15 K (K*/"#$)

'si"p$ic (K*/"#$)

O

5

10

15

20

25

30

(,) 5483.1928038027, + 5.1419420165

1

Cu(+2a)+HS(-a)=CuS+H(+a)

# ()


6/8

# () + (1/T)

5.1419 5483.2

% error

98.2691970042 0.0008171322

-104.7919370298 0.000131241

Sp#"ei# */"#$

Hp#"ei# K*/"#$

0.0038 0.0026 0.0028 0.003 0.0032 0.0034 0.0

1/T


7/8


8/8

36 0.0038

(2013-II) logk (3 reacciones)

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